Concrete Chemical Admixtures
Chemical admixtures are materials in the form of powder or fluids that are added to the concrete to give it certain characteristics not obtainable with plain concrete mixes. In normal use, admixture dosages are less than 5% by mass of cement, and are added to the concrete at the time of batching/mixing. The common types of admixtures are as follows.
- Accelerators speed up the hydration, or hardening, of the concrete. Typical materials used are CaCl2 and NaCl. However, use of chlorides may cause corrosion in steel reinforcing and is prohibited in some countries.
- Retarders slow the hydration of concrete, and are used in large or difficult pours where partial setting before the pour is complete is undesirable. Typical polyol retarders are sugar, sucrose, sodium gluconate, glucose, citric acid, and tartaric acid.
- Air entrainments add and entrain tiny air bubbles in the concrete, which will reduce damage during freeze-thaw cycles thereby increasing the concrete's durability. However, entrained air is a trade-off with strength, as each 1% of air may result in 5% decrease in compressive strength.
- Plasticizers increase the workability of plastic or fresh concrete, allowing it be placed more easily, with less consolidating effort. Typical plasticizers are lignosulfonate. Plasticizers can be used to reduce the water content of a concrete while maintaining workability, and are sometimes called water-reducers due to this use. Such treatment improves its strength and durability characteristics. Superplasticizers also called high-range water-reducers, are a class of plasticizers that have fewer deleterious effects, and can be used to increase workability more than practical with traditional plasticizers. Compounds used as superplasticizers include sulfonated naphthalene formaldehyde condensate, sulfonated melamine formaldehyde condensate, acetone formaldehyde condensate, and polycarboxylate ethers.
- Pigments can be used to change the color of concrete, for aesthetics.
- Corrosion inhibitors are used to minimize the corrosion of steel and steel bars in concrete.
- Bonding agents are used to create a bond between old and new concrete.
- Pumping aids improve pumpability, thicken the paste, and reduce separation and bleeding.
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Fly ash: A by product of coal fired electric generating plants, it is used to partially replace Portland cement (by up to 60% by mass). The properties of fly ash depend on the type of coal burnt. In general, silicious fly ash is pozzolanic, while calcareous fly ash has latent hydraulic properties.
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Ground granulated blast furnace slag: A by-product of steel production is used to partially replace Portland cement by up to 80% by mass. It has latent hydraulic properties.
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Silica fume: A by-product of the production of silicon and ferrosilicon alloys. Silica fume is similar to fly ash, but has a particle size 100 times smaller. This results in a higher surface to volume ratio and a much faster pozzolanic reaction. Silica fume is used to increase strength and durability of concrete, but generally requires the use of superplasticizers for workability.
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High reactivity Metakaolin (HRM): Metakaolin produces concrete with strength and durability similar to concrete made with silica fume. While silica fume is usually dark gray or black in color, high reactivity metakaolin is usually bright white in color, making it the preferred choice for architectural concrete where appearance is important.
Contact:
Claude Leeder
8310 HILLMONT
HOUSTON TX 77040
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